Chin. Phys. Lett.  2006, Vol. 23 Issue (10): 2838-2840    DOI:
Original Articles |
Effects of Processing Parameters on Microstructure and Properties of Nanoscale ZrC/ZrB2 Multilayered Coatings
YANG Jin;ZHANG Xue-Hua;CAO Meng;WANG Ming-Xia;LIANG Jin-Ling;LI De-Jun
College of Physics and Electronic Information Science, Tianjin Normal University, Tianjin 300074
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YANG Jin, ZHANG Xue-Hua, CAO Meng et al  2006 Chin. Phys. Lett. 23 2838-2840
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Abstract ZrC/ZrB2 multilayered coatings with bilayer periods of 3.5--40nm are synthesized by rf magnetron sputtering. Analyses of x-ray diffraction, scanning electron microscopy and nanoindentation indicate that multilayered coatings possess much higher hardness and greater fracture resistance than monolithic ZrC and ZrB2 coatings. A maximum hardness (41.7GPa) and a critical fracture load (73.7mN) are observed in the multilayer with La=32nm deposited at the substrate bias -40V. Higher residual stress built in the ZrC layer can be released by periodic insertion of ZrB2 into the ZrC layer. A clear multilayered structure with mixed ZrB2 (001), ZrB2 (002) and ZrC (111) orientations should be responsible for the enhanced mechanical properties.
Keywords: 68.65.Ac      81.15.Cd      81.65.Lp      81.65.Lp     
Published: 01 October 2006
PACS:  68.65.Ac (Multilayers)  
  81.15.Cd (Deposition by sputtering)  
  81.65.Lp (Surface hardening: nitridation, carburization, carbonitridation ?)  
  81.65.Lp (Surface hardening: nitridation, carburization, carbonitridation ?)  
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https://cpl.iphy.ac.cn/       OR      https://cpl.iphy.ac.cn/Y2006/V23/I10/02838
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YANG Jin
ZHANG Xue-Hua
CAO Meng
WANG Ming-Xia
LIANG Jin-Ling
LI De-Jun
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