Thermal Expansion of CsNiCI<suB>3</suB> by Electron Paramagnetic Resonance and Optical Absorption Spectra

Chin. Phys. Lett.

2000, Vol. 17

Issue (6): 448-450 DOI:

Original Articles

Thermal Expansion of CsNiCI₃ by Electron Paramagnetic Resonance and Optical Absorption Spectra

GUO Sheng-Li^1,2;ZHANG Yong²;YOU Xiao-Zeng²;MIN Nai-Ben¹

¹State Key Laboratory of Solid State Microstructures and Department of Physics, ²Institute of Coordination Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093

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GUO Sheng-Li, ZHANG Yong, YOU Xiao-Zeng et al 2000 Chin. Phys. Lett. 17 448-450

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Abstract Electron paramagnetic resonance (EPR) measurement of CsNiCl₃ compound has been performed at 192 GHz in the temperature range from 300 to 5K, along the axes of main g tensor. The energy levels and the g-factors are calculated. The linear thermal expansion coefficient ( 2.77x10^-5 K^-1 ) for the Ni²⁺-CI^- bond distance is studied by combining EPR and optical absorption spectra with changing temperature.

Keywords: 76.30.Fc 71.70.Ch

Published: 01 June 2000

PACS:	76.30.Fc	(Iron group (3d) ions and impurities (Ti-Cu))
	71.70.Ch	(Crystal and ligand fields)

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https://cpl.iphy.ac.cn/ OR https://cpl.iphy.ac.cn/Y2000/V17/I6/0448

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	GUO Sheng-Li
	ZHANG Yong
	YOU Xiao-Zeng
	MIN Nai-Ben

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