Chin. Phys. Lett.  2012, Vol. 29 Issue (4): 047502    DOI: 10.1088/0256-307X/29/4/047502
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
Size Segregation and Super-Domain Mediated by Dipolar Interactions in 3-D Iron Nanoparticle Assemblies
SI Ping-Zhan1**,WANG Hai-Xia1,JIANG Wei1,CHEN Chun-Qiang1,HU Xiu-Kun1,LIU Jin-Jun2,LEE Jung-Goo3,CHOI Chul-Jin3
1School of Materials Science and Engineering, China Jiliang University, Hangzhou 310018
2Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211
3Korea Institute of Materials Science, Changwon, Gyeongnam, 641-831, R. Korea
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SI Ping-Zhan**, WANG Hai-Xia, JIANG Wei et al  2012 Chin. Phys. Lett. 29 047502
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Abstract We report the phenomenon of size segregation and the experimental evidence for the presence of correlated areas mediated by dipolar interactions in three-dimensional Fe nanoparticle assemblies. Iron nanoparticles dispersed in ethanol assemble into tabular whiskers (8µm×40µm in cross section with lengths up to 10 cm) due to dipolar interactions. Magnetic force microscopy observations on iron nanoparticle compact assemblies prove the local magnetic correlation of the Fe nanoparticles due to dipolar coupling and the formation of domain-like structures in expanded dimensions. Magnetic measurements show that the coercivity and the low field magnetic susceptibility of the Fe nanoparticle assemblies increase while the saturation magnetization decreases with the increasing inter-particle distance.
Keywords: 75.75.Fk      68.37.Hk     
Received: 27 September 2011      Published: 04 April 2012
PACS:  75.75.Fk (Domain structures in nanoparticles)  
  68.37.Hk (Scanning electron microscopy (SEM) (including EBIC))  
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https://cpl.iphy.ac.cn/10.1088/0256-307X/29/4/047502       OR      https://cpl.iphy.ac.cn/Y2012/V29/I4/047502
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SI Ping-Zhan**
WANG Hai-Xia
JIANG Wei
CHEN Chun-Qiang
HU Xiu-Kun
LIU Jin-Jun
LEE Jung-Goo
CHOI Chul-Jin
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