Chin. Phys. Lett.  2012, Vol. 29 Issue (12): 123101    DOI: 10.1088/0256-307X/29/12/123101
ATOMIC AND MOLECULAR PHYSICS |
Stereodynamics Study of Li+HF/DF/TF→LiF+H/D/T Reactions on X2A' Potential Energy Surface
TAN Rui-Shan, LIU Xin-Guo**, HU Mei
College of Physics and Electronics, Shandong Normal University, Jinan 250014
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TAN Rui-Shan, LIU Xin-Guo, HU Mei 2012 Chin. Phys. Lett. 29 123101
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Abstract

The product rotational polarizations of reactions Li+HF/DF/TF at different collision energies are calculated using the quasi-classical trajectory method based on a new potential energy surface constructed by Aguado and Paniagua [J. Chem. Phys. 119 (2003) 10088]. We investigate the P(θr) distributions describing the kj' correlation, the P(φr) distributions describing the kk'j' correlation, and the four polarization-dependent generalized differential cross sections. Furthermore, we compare the influences of mass factor and collision energy in detail and find that the isotope substitution has more impact on the distribution of the product's angular momentum vectors than the collision energy.

Received: 08 October 2012      Published: 04 March 2013
PACS:  31.15.ap (Polarizabilities and other atomic and molecular properties)  
  31.15.at (Molecule transport characteristics; molecular dynamics; electronic structure of polymers)  
  34.50.Lf (Chemical reactions)  
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https://cpl.iphy.ac.cn/10.1088/0256-307X/29/12/123101       OR      https://cpl.iphy.ac.cn/Y2012/V29/I12/123101
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TAN Rui-Shan
LIU Xin-Guo
HU Mei
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