Chin. Phys. Lett.  2009, Vol. 26 Issue (12): 127801    DOI: 10.1088/0256-307X/26/12/127801
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
Ultrafast Photophysics of Star-Like Molecules with Benzene and Triazine Core
FENG Wen-Ke1, KONG Sheng1, XIAO Li-Xin1, MENG Kang1, WANG Shu-Feng1, GONG Qi-Huang1
State Key Laboratory for Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871
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FENG Wen-Ke, KONG Sheng, XIAO Li-Xin et al  2009 Chin. Phys. Lett. 26 127801
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Abstract Static and transient spectroscopic characters of newly synthesized start-like molecules, 1,3,5-tri(10-butyl-3-propenyl-10H-phenothiazine)-benzene (TP3B) and 2,4,6-tri(10-butyl-3-propenyl -10H-phenothiazine)-[1,3,5]triazine (TP3T), are studied using static, picosecond fluorescence and femtosecond transient absorption spectroscopy. The results show that when the benzene group is in the center, a large conjugation system is formed, while a fast electron-transfer process happens when the center group is triazine.
Keywords: 78.40.Me      78.47.Cd      78.47.jc     
Received: 02 September 2009      Published: 27 November 2009
PACS:  78.40.Me (Organic compounds and polymers)  
  78.47.Cd  
  78.47.jc  
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https://cpl.iphy.ac.cn/10.1088/0256-307X/26/12/127801       OR      https://cpl.iphy.ac.cn/Y2009/V26/I12/127801
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FENG Wen-Ke
KONG Sheng
XIAO Li-Xin
MENG Kang
WANG Shu-Feng
GONG Qi-Huang
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